Diastereoselective Synthesis of cis-α,α′-Disubstituted Cyclic Ethers via Borane-Catalyzed Reductive Cyclization of Diketones ( @pubs.acs.org ): pubs.acs.org/doi/full/10.... ( @jmasrosello.bsky.social ).
January 7, 2026 at 10:30 AM
Diastereoselective Synthesis of cis-α,α′-Disubstituted Cyclic Ethers via Borane-Catalyzed Reductive Cyclization of Diketones ( @pubs.acs.org ): pubs.acs.org/doi/full/10.... ( @jmasrosello.bsky.social ).
Kwon, Katturi, Moreno, C\'ardenas, Dantus: Ultrafast cation-dication dynamics in ammonia borane: H-migration to roaming H2 and reduced H3+ formation under strong-field ionization https://arxiv.org/abs/2601.02510 https://arxiv.org/pdf/2601.02510 https://arxiv.org/html/2601.02510
January 7, 2026 at 6:47 AM
Kwon, Katturi, Moreno, C\'ardenas, Dantus: Ultrafast cation-dication dynamics in ammonia borane: H-migration to roaming H2 and reduced H3+ formation under strong-field ionization https://arxiv.org/abs/2601.02510 https://arxiv.org/pdf/2601.02510 https://arxiv.org/html/2601.02510
Mahmoud Deeb, Nabil Joudieh, Nidal Chamoun, Habib Abboud: Quantum Study of Halogen Substituted anti-B18H22 Borane Clusters for Optoelectronics https://arxiv.org/abs/2601.02013 https://arxiv.org/pdf/2601.02013 https://arxiv.org/html/2601.02013
January 6, 2026 at 6:46 AM
Mahmoud Deeb, Nabil Joudieh, Nidal Chamoun, Habib Abboud: Quantum Study of Halogen Substituted anti-B18H22 Borane Clusters for Optoelectronics https://arxiv.org/abs/2601.02013 https://arxiv.org/pdf/2601.02013 https://arxiv.org/html/2601.02013
“She runs on toxic HEX-BH borane sludge, lifts two hundred tons, and still makes GEO and back on one tank. Brownwash gets the mechs down alive. Armor’s thick enough, systems are old, and everything important is bolted in place. That’s the whole trick.”
December 27, 2025 at 10:26 PM
“She runs on toxic HEX-BH borane sludge, lifts two hundred tons, and still makes GEO and back on one tank. Brownwash gets the mechs down alive. Armor’s thick enough, systems are old, and everything important is bolted in place. That’s the whole trick.”
Tris(pentafluorophenyl)borane Catalyzed Stereoselective Synthesis of β-O-Aryl Glycosides from Armed and Disarmed Glycosylimidate Donors ( @pubs.acs.org ): pubs.acs.org/doi/10.1021/....
December 26, 2025 at 8:37 PM
Tris(pentafluorophenyl)borane Catalyzed Stereoselective Synthesis of β-O-Aryl Glycosides from Armed and Disarmed Glycosylimidate Donors ( @pubs.acs.org ): pubs.acs.org/doi/10.1021/....
X-ray-diffraction and electrical-transport imaging of superconducting superhydride (La,Y)H10
https://www.europesays.com/ie/244833/
Structural characterization of (La,Y)H10 Prior to laser heating, the La0.9Y0.1 alloy compressed together with ammonia borane (NH3BH3) to…
https://www.europesays.com/ie/244833/
Structural characterization of (La,Y)H10 Prior to laser heating, the La0.9Y0.1 alloy compressed together with ammonia borane (NH3BH3) to…
X-ray-diffraction and electrical-transport imaging of superconducting superhydride (La,Y)H10 - Ireland
Structural characterization of (La,Y)H10
www.europesays.com
December 21, 2025 at 8:30 PM
X-ray-diffraction and electrical-transport imaging of superconducting superhydride (La,Y)H10
https://www.europesays.com/ie/244833/
Structural characterization of (La,Y)H10 Prior to laser heating, the La0.9Y0.1 alloy compressed together with ammonia borane (NH3BH3) to…
https://www.europesays.com/ie/244833/
Structural characterization of (La,Y)H10 Prior to laser heating, the La0.9Y0.1 alloy compressed together with ammonia borane (NH3BH3) to…
Excited to share that our latest preprint on direct ester-to-ether
reduction using fiddler crab-type borane catalysts is featured in this
month's OPR&D literature review by @pubs.acs.org 🦀⚗️
Great to see early interest from the process R&D community!
doi.org/10.1021/acs....
reduction using fiddler crab-type borane catalysts is featured in this
month's OPR&D literature review by @pubs.acs.org 🦀⚗️
Great to see early interest from the process R&D community!
doi.org/10.1021/acs....
Some Items of Interest to Process R&D Chemists and Engineers
This publication is free to access through this site.
Learn More
doi.org
December 17, 2025 at 3:26 PM
Excited to share that our latest preprint on direct ester-to-ether
reduction using fiddler crab-type borane catalysts is featured in this
month's OPR&D literature review by @pubs.acs.org 🦀⚗️
Great to see early interest from the process R&D community!
doi.org/10.1021/acs....
reduction using fiddler crab-type borane catalysts is featured in this
month's OPR&D literature review by @pubs.acs.org 🦀⚗️
Great to see early interest from the process R&D community!
doi.org/10.1021/acs....
Recent research by Viktor O. Iaroshenko 𝘦𝘵 𝘢𝘭.
#MatejBelUniversity
This study presents an improved reduction of nitroarenes to anilines using cucurbit[7]uril and ammonia borane, marking progress in photochemical supramolecular catalysis.
doi.org/10.1039/D5QO01451D
#MatejBelUniversity
This study presents an improved reduction of nitroarenes to anilines using cucurbit[7]uril and ammonia borane, marking progress in photochemical supramolecular catalysis.
doi.org/10.1039/D5QO01451D
Photo and mechanochemically induced reduction of nitroarenes using ammonia borane
This study presents an advanced approach for the reduction of nitroarenes to anilines, employing cucurbit[7]uril as a catalyst and ammonia borane as a hydrogen source, signifying noteworthy progressio...
doi.org
December 11, 2025 at 7:52 AM
Recent research by Viktor O. Iaroshenko 𝘦𝘵 𝘢𝘭.
#MatejBelUniversity
This study presents an improved reduction of nitroarenes to anilines using cucurbit[7]uril and ammonia borane, marking progress in photochemical supramolecular catalysis.
doi.org/10.1039/D5QO01451D
#MatejBelUniversity
This study presents an improved reduction of nitroarenes to anilines using cucurbit[7]uril and ammonia borane, marking progress in photochemical supramolecular catalysis.
doi.org/10.1039/D5QO01451D
Mechanically Transformed ZIF-67 Phases as Catalytically Active Nanomaterials for Ammonia Borane Hydrolysis http://dx.doi.org/10.1021/acsanm.5c04316
November 14, 2025 at 2:12 PM
Mechanically Transformed ZIF-67 Phases as Catalytically Active Nanomaterials for Ammonia Borane Hydrolysis http://dx.doi.org/10.1021/acsanm.5c04316
Another cover from the latest issue of #JACS: ‘Mechanistic Insights into the Borane-Mediated Conversion of 5-Carboxylcytosine to Dihydrouracil in DNA Enable an Efficient Labeling Method Using Alkoxyamines’.
Explore the research behind the art: buff.ly/UssmGkS
Explore the research behind the art: buff.ly/UssmGkS
November 11, 2025 at 1:01 PM
Another cover from the latest issue of #JACS: ‘Mechanistic Insights into the Borane-Mediated Conversion of 5-Carboxylcytosine to Dihydrouracil in DNA Enable an Efficient Labeling Method Using Alkoxyamines’.
Explore the research behind the art: buff.ly/UssmGkS
Explore the research behind the art: buff.ly/UssmGkS
ICYMI: Reductive Aminations of Carbonyl Compounds with Borohydride and Borane Reducing Agents
Reductive Aminations of Carbonyl Compounds with Borohydride and Borane Reducing Agents
Reductive amination is an important tool for synthetic organic chemists in the construction of carbon-nitrogen bonds. This reaction, also termed reductive alkylation, involves condensation of an aldehyde or ketone with an amine in the prese...
eurekamag.com
November 11, 2025 at 5:56 AM
ICYMI: Reductive Aminations of Carbonyl Compounds with Borohydride and Borane Reducing Agents
Reductive Aminations of Carbonyl Compounds with Borohydride and Borane Reducing Agents
Reductive Aminations of Carbonyl Compounds with Borohydride and Borane Reducing Agents
Reductive amination is an important tool for synthetic organic chemists in the construction of carbon-nitrogen bonds. This reaction, also termed reductive alkylation, involves condensation of an aldehyde or ketone with an amine in the prese...
eurekamag.com
November 10, 2025 at 5:55 AM
Reductive Aminations of Carbonyl Compounds with Borohydride and Borane Reducing Agents
Researchers in China claim to have made the first ever room-temperature superconductor by compressing an alloy of lanthanum-scandium and the hydrogen-rich material ammonia borane together at pressures of 250–260 GPa. 🧪⚛️
physicsworld.com/a/ternary-hy...
physicsworld.com/a/ternary-hy...
Ternary hydride shows signs of room-temperature superconductivity at high pressures – Physics World
New alloy is made by doping scandium into the well-known La-H binary system
physicsworld.com
November 7, 2025 at 9:52 AM
Researchers in China claim to have made the first ever room-temperature superconductor by compressing an alloy of lanthanum-scandium and the hydrogen-rich material ammonia borane together at pressures of 250–260 GPa. 🧪⚛️
physicsworld.com/a/ternary-hy...
physicsworld.com/a/ternary-hy...
Now online:
Article by Chengjian Zhang, Xinghong Zhang & co-workers
Air-stable covalent borane–oxyanion organocatalysts for ring-opening copolymerization
www.nature.com/articles/s44... ($)
#Chemsky
Article by Chengjian Zhang, Xinghong Zhang & co-workers
Air-stable covalent borane–oxyanion organocatalysts for ring-opening copolymerization
www.nature.com/articles/s44... ($)
#Chemsky
Air-stable covalent borane–oxyanion organocatalysts for ring-opening copolymerization - Nature Synthesis
Covalently tethered borane–oxyanion organocatalysts enable highly efficient ring-opening copolymerization of epoxides and cyclic anhydrides via intramolecular cooperation, achieving turnover frequenci...
www.nature.com
November 6, 2025 at 5:24 PM
Now online:
Article by Chengjian Zhang, Xinghong Zhang & co-workers
Air-stable covalent borane–oxyanion organocatalysts for ring-opening copolymerization
www.nature.com/articles/s44... ($)
#Chemsky
Article by Chengjian Zhang, Xinghong Zhang & co-workers
Air-stable covalent borane–oxyanion organocatalysts for ring-opening copolymerization
www.nature.com/articles/s44... ($)
#Chemsky
📣We are happy to announce an interesting publication from @samanthafrank.bsky.social in cooperation with Dr. Zoltán Benkő (University of Budapest) on the C-N single bond activation by a Phosphinine-Borane Lewis pair
Congrats to all authors..🎉
chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...
Congrats to all authors..🎉
chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...
chemistry-europe.onlinelibrary.wiley.com
October 28, 2025 at 12:42 PM
📣We are happy to announce an interesting publication from @samanthafrank.bsky.social in cooperation with Dr. Zoltán Benkő (University of Budapest) on the C-N single bond activation by a Phosphinine-Borane Lewis pair
Congrats to all authors..🎉
chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...
Congrats to all authors..🎉
chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...
www.organic-chemistry.org/abstracts/li...
Ammonia-borane serves as an efficient precatalyst for the direct amidation of both aromatic and aliphatic carboxylic acids.
Ammonia-borane serves as an efficient precatalyst for the direct amidation of both aromatic and aliphatic carboxylic acids.
October 14, 2025 at 10:26 AM
www.organic-chemistry.org/abstracts/li...
Ammonia-borane serves as an efficient precatalyst for the direct amidation of both aromatic and aliphatic carboxylic acids.
Ammonia-borane serves as an efficient precatalyst for the direct amidation of both aromatic and aliphatic carboxylic acids.
[30/30] 134 Likes, 72 Comments, 2 Posts
2510.01273, cond-mat․supr-con, 29 Sep 2025
🆕Room-Temperature Superconductivity at 298 K in Ternary La-Sc-H System at High-pressure Conditions
Yinggang Song, Chuanheng Ma, Hongbo Wang, Mi Zhou, Yanpeng Qi, Weizheng Cao, Shourui Li, Hanyu Liu, Guangtao Li...
2510.01273, cond-mat․supr-con, 29 Sep 2025
🆕Room-Temperature Superconductivity at 298 K in Ternary La-Sc-H System at High-pressure Conditions
Yinggang Song, Chuanheng Ma, Hongbo Wang, Mi Zhou, Yanpeng Qi, Weizheng Cao, Shourui Li, Hanyu Liu, Guangtao Li...
October 6, 2025 at 12:05 AM
[30/30] 134 Likes, 72 Comments, 2 Posts
2510.01273, cond-mat․supr-con, 29 Sep 2025
🆕Room-Temperature Superconductivity at 298 K in Ternary La-Sc-H System at High-pressure Conditions
Yinggang Song, Chuanheng Ma, Hongbo Wang, Mi Zhou, Yanpeng Qi, Weizheng Cao, Shourui Li, Hanyu Liu, Guangtao Li...
2510.01273, cond-mat․supr-con, 29 Sep 2025
🆕Room-Temperature Superconductivity at 298 K in Ternary La-Sc-H System at High-pressure Conditions
Yinggang Song, Chuanheng Ma, Hongbo Wang, Mi Zhou, Yanpeng Qi, Weizheng Cao, Shourui Li, Hanyu Liu, Guangtao Li...
Research Highlight now online:
Hydrogenation using ammonia-borane by @peterseavill.bsky.social
www.nature.com/articles/s44... ($)
Highlighting the @cp-chem.bsky.social article by Michael J. Tilby, Daniele Leonori and co-workers
#Chemsky
Hydrogenation using ammonia-borane by @peterseavill.bsky.social
www.nature.com/articles/s44... ($)
Highlighting the @cp-chem.bsky.social article by Michael J. Tilby, Daniele Leonori and co-workers
#Chemsky
Hydrogenation using ammonia-borane - Nature Synthesis
Nature Synthesis - Hydrogenation using ammonia-borane
www.nature.com
October 1, 2025 at 8:58 AM
Research Highlight now online:
Hydrogenation using ammonia-borane by @peterseavill.bsky.social
www.nature.com/articles/s44... ($)
Highlighting the @cp-chem.bsky.social article by Michael J. Tilby, Daniele Leonori and co-workers
#Chemsky
Hydrogenation using ammonia-borane by @peterseavill.bsky.social
www.nature.com/articles/s44... ($)
Highlighting the @cp-chem.bsky.social article by Michael J. Tilby, Daniele Leonori and co-workers
#Chemsky
Interested in metal-ligand cooperation for dehydrocoupling reactions? Check out Mirkos latest paper on late transition metal PN(H)N pincer complexes in amine borane chemistry. Now online in EurJIC. @likat.bsky.social chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...
PNN‐Type Pincer Imidazolylphosphine Complexes of Late Transition Metals for the Catalytic Dehydrocoupling of Amine Boranes
A systematic study is presented of the coordination chemistry of imidazolylphosphine-based PN(H)N pincer ligands at Rh, Ir, and Ru centers. The corresponding cationic complexes are active catalysts f....
chemistry-europe.onlinelibrary.wiley.com
September 24, 2025 at 7:38 AM
Interested in metal-ligand cooperation for dehydrocoupling reactions? Check out Mirkos latest paper on late transition metal PN(H)N pincer complexes in amine borane chemistry. Now online in EurJIC. @likat.bsky.social chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...
These findings provide valuable design principles for developing more efficient amine-borane photocatalysts for sustainable reduction reactions.
September 14, 2025 at 5:50 AM
These findings provide valuable design principles for developing more efficient amine-borane photocatalysts for sustainable reduction reactions.
Using DFT and multiconfigurational ab initio simulations, the researchers demonstrate that upon UV-A light absorption, the amine-borane model system populates a low-lying triplet state, which then enables the reduction of carbon-carbon double bonds through remarkably low activation barriers, an o...
September 14, 2025 at 5:50 AM
Using DFT and multiconfigurational ab initio simulations, the researchers demonstrate that upon UV-A light absorption, the amine-borane model system populates a low-lying triplet state, which then enables the reduction of carbon-carbon double bonds through remarkably low activation barriers, an o...
Wade's Rules introductions by textbook:
Weller et al: consider these MOs
Housecroft & Sharpe: consider these structures
Greenwood & Earnshaw: ok so this is how you number the positions on a substituted conjunto-borane
Weller et al: consider these MOs
Housecroft & Sharpe: consider these structures
Greenwood & Earnshaw: ok so this is how you number the positions on a substituted conjunto-borane
September 12, 2025 at 11:27 AM
Wade's Rules introductions by textbook:
Weller et al: consider these MOs
Housecroft & Sharpe: consider these structures
Greenwood & Earnshaw: ok so this is how you number the positions on a substituted conjunto-borane
Weller et al: consider these MOs
Housecroft & Sharpe: consider these structures
Greenwood & Earnshaw: ok so this is how you number the positions on a substituted conjunto-borane
Online now: Photocatalytic hydrogenation of alkenes using ammonia-borane
Photocatalytic hydrogenation of alkenes using ammonia-borane
Hydrogenation of olefins is a key reaction in chemistry; however, it typically requires the use of flammable hydrogen gas with transition metal catalysis. This work presents a novel approach employing ammonia-borane, a stable and non-toxic reagent, as a hydrogen surrogate material under photocatalytic conditions, which efficiently circumvents the use of hydrogen and metal catalysis.
dlvr.it
August 25, 2025 at 3:34 PM
Online now: Photocatalytic hydrogenation of alkenes using ammonia-borane
Dive into N-heterocyclic carbene #borane Type I photoinitiators! Lalevée, Lacôte & co-workers achieved the first homolytic B–N bond #cleavage, enabling new PIs with rapid #photolysis and outstanding #polymerization. A breakthrough for high-performance applications🤯
👉 buff.ly/PKAo1Pc
👉 buff.ly/PKAo1Pc
August 1, 2025 at 7:01 AM
Dive into N-heterocyclic carbene #borane Type I photoinitiators! Lalevée, Lacôte & co-workers achieved the first homolytic B–N bond #cleavage, enabling new PIs with rapid #photolysis and outstanding #polymerization. A breakthrough for high-performance applications🤯
👉 buff.ly/PKAo1Pc
👉 buff.ly/PKAo1Pc