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The straightforward synthesis of new thiazolylidene gold complexes is described. Despite their decreased steric protection, these complexes demonstrate excellent stability and high catalytic activity ...

Current Employees: If you are currently employed at any of the Universities of Wisconsin, log in to Workday to apply through the internal application process.Job Category:FacultyEmployment Type:Regula...

✨ SUPERLASER consortium meets in Linköping! ✨ Last week, the SUPERLASER consortium gathered at Linköping University, Sweden for the first annual progress meeting. Two intense days of presentations, d...

On July 16, 2025, a Memorandum of Understanding was signed between the National and Kapodistrian University of Athens (NKUA) and Henan University. The

Fullerene-based donor-acceptor (D-A) dyads have been extensively studied for their unique electronic properties, with applications in photoinduced energy conversion devices. In these systems, dynamic...

A highly efficient, in situ formed CuCl2/TMEDA catalytic system (TMEDA = N,N,N′,N′-tetramethylethylene-diamine) for the cross-coupling reaction of aryl acetonitriles with benzyl alcohols is reported. This user-friendly protocol, employing a low catalyst loading and a catalytic amount of base, leads to the synthesis of α-alkylated nitriles in up to 99% yield. Experimental mechanistic investigations reveal that the key step of this transformation is the C(sp3)–H functionalization of the alcohol, taking place via a hydrogen atom abstraction, with the simultaneous formation of copper-hydride species. Detailed density functional theory studies shed light on all reaction steps, confirming the catalytic pathway proposed on the basis of the experimental findings.

In the face of recent abrupt shifts in federal funding for education research, including large-scale terminations of National Science Foundation (NSF) research grant awards, we have developed a rap...

Learn more about applying for Senior Director, Medicinal Chemistry Strategy at AstraZeneca

Job Title: Associate or Senior Editor (Organic Chemistry), Nature Communications Organisation: Nature Portfolio Locations: Jersey City, London, New York, Philadelphia or Washington DC - hybrid working...

🔦 Light Meets Precision With A Click – The Journey Begins On March 20-21, the six #SCALPEL partners from across Europe came together in Oslo, Norway to…

A base-catalyzed protocol is reported for the construction of 1,3-thiazolidine-2-thione scaffolds bearing quaternary carbon centers from carbon disulfide and α-tertiary propargylamines. The reaction proceeds using low catalyst loading, under ambient temperatures, and in the absence of solvent. Various α-tertiary propargylamines have been employed, affording a series of previously unreported thiazolidine-2-thione compounds and avoiding purification via column chromatography in certain cases. We also describe a one-pot strategy for the synthesis of the same products through a KA2 coupling–CS2 incorporation approach. The reaction mechanism and substituent-dependent catalytic behavior were studied through a combination of detailed experimental and computational studies.

✨ Lighting Up a New Era in Cancer Treatment ✨   We are excited to introduce #SCALPEL – a #groundbreaking, Europe-wide initiative that is set to redefine…

In response to the need for sustainable energy, this study focuses on advancing the electrocatalytic Hydrogen Evolution Reaction (HER). Considering platinum-based catalysts’ efficacy, but acknowledging their cost and scarcity implications, our work pursues Pt content minimization, simultaneously upholding catalytic efficiency. Our approach introduces a precisely engineered nanoarchitecture, leveraging multiwalled carbon nanotubes (MWCNTs) bearing anchored N-heterocyclic carbenes (NHCs). These carbenes form robust covalent bonds with ultrastable, highly crystalline, platinum nanoparticles (PtNPs), establishing MWCNTs-NHC-PtNPs as a highly efficient electrocatalyst. The synergistic effect of NHCs and triazole moieties facilitates controlled nanoparticle growth and stabilization, yielding 2.0 ± 0.3 nm, uniformly distributed {1 1 1}-faceted PtNPs. The as-obtained MWCNTs-NHC-PtNPs nanomaterial exhibits exceptional HER efficiency in 0.5 M H2SO4 with an overpotential of 77 mV at −10 mA cm–2 and a 50 mV dec–1 Tafel slope, despite containing a merely 0.4% Pt/C atomic ratio content, as determined by XPS. Notably, at 200 mV overpotential, the mass activity reaches 8.6 A/mgPt and the specific activity is 53 mA/cm2Pt, highlighting the efficiency of each Pt site within this nanostructure. Cyclic voltammetry reveals a distinctive, reversible PtO/Pt redox process, demonstrating surface-controlled and diffusion-assisted kinetics with charge storage properties that stabilize the electrocatalyst’s electron-surface and facilitate proton reduction. Equally important, the nanoarchitecture prevents aggregation and mitigates Pt irreversible oxidation, showcasing enhanced stability after extensive cycling and exposure to air. Comparative analyses with a control electrocatalyst lacking NHC-PtNPs ligation emphasize the unique role of NHC-Pt (0) bonding in enhancing electrocatalytic efficiency. Comprehensive surface and electronic property analyses validate the potential of the MWCNTs-NHC-PtNPs platform.

Posted 9:23:25 PM. The Department of Chemistry at Queen's University invites applicants for a tenure-track faculty…See this and similar jobs on LinkedIn.

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