Martín-Olalla, José María
martin-olallajm.bsky.social
Martín-Olalla, José María
@martin-olallajm.bsky.social
Thinking out of the box on seasonal daylight saving time. It is latitude.

https://zenodo.org/communities/dst/records?q=&l=list&p=1&s=10&sort=publication-desc
19. In the unlikely event that you managed to get to this endpoint, please kindly consider to republish the first comment in this thread:

bsky.app/profile/mart...

🔚 @unisevilla.bsky.social @fisicaus.bsky.social
Physica Scripta (IOP Pub) releases my work linking the vanishing of the specific heats at absolute zero with the principle of entropy increase. doi.org/10.1088/1402... It continues my previous work on Nernst theorem and completes a revision of the 3rd law of thermodynamics.🆕🧵⤵️
December 11, 2025 at 7:14 AM
18. This work originated from a chat with @ccuanticos.bsky.social
(Enrique Fernández Borja) on Youtube

youtube.com/watch?v=piz9... (1h20min, read also commentaries) on the Nernst theorem.
120 Años bajo la sombra de Einstein: Entrevista al Profesor José María Martín Olalla.
YouTube video by CUENTOS CUÁNTICOS
youtube.com
December 11, 2025 at 7:12 AM
17. Preprint version (and translation into Spanish) is available at doi.org/10.5281/zeno... and the institutional repository hdl.handle.net/11441/179315

The accepted manuscript (and translation) is available at my personal page personal.us.es/olalla
Thermal stability originates the vanishing of the specific heats at absolute zero
The relationship between the vanishing of the heat capacities as $T\to0^+$ and the thermal stability is examined. The heat capacities vanish as fast as or faster than $T$ as $T\to0^+$ for states at th...
doi.org
December 11, 2025 at 7:11 AM
16. My conclusion: we do not need a new law to codify this behaviour. The general properties of matter at absolute zero can be deduced from the two main laws of thermodynamics.
December 11, 2025 at 7:10 AM
15. Back to curvature. At T=0, U(S) has zero slope. Therefore, the issue is how much flat U(S) can be to sustain stability. Conditions shallower than a parabola would not sustain stability and are abhorred. Conditions stiffer than a parabola are welcome.
December 11, 2025 at 7:10 AM
14. A non-varying specific heat [the old, venerable Dulong-Petit law] in T->0 would yield an exponential loss of curvature. The system would trigger extremely large critical fluctuations. Nature just abhors putting itself in such jeopardy.
December 11, 2025 at 7:09 AM
13. But in T->0, a weakly vanishing C suffices to provide curvature loss. As an example C~√T does not sustain the stability condition at T=0. Strongly correlated systems exhibit this behaviour named quantum critical point (QCP): a critical behaviour precisely at T=0.
December 11, 2025 at 7:09 AM
12. In standard T>0 conditions, the loss of stability is associated with curvature loss in u(s). This requires C increasing indefinitely to infinity, giving rise to critical fluctuations and critical phenomena. Watch this (unrelated to the specific heat) youtube.com/watch?v=VGxW...
Critical point and critical opalescence. Punto crítico y opalescencia crítica.
YouTube video by José María Martín-Olalla
youtube.com
December 11, 2025 at 7:08 AM
11. Usual observations in crystalline solids, electronic contribution, and son on, and useful models (Debye, Sommerfeld, Schottky) go in line with this result. They are not alien to the 2nd law but an ultimate consequence of the 2nd law of thermodynamics.
December 11, 2025 at 7:07 AM
10. But, if T->0, then the standard condition changes into "C must vanish as fast as T or faster". C~T^3 is ok, C~T, also; but C~√T is not ok with stability at absolute zero. This is new in doi.org/10.1088/1402...
December 11, 2025 at 7:06 AM
9. Therefore, at non-zero temperature T>0 the standard stability condition is read as: C must be finite, positive for thermal stability to sustain. Every textbook in thermodynamics goes in this line.
December 11, 2025 at 7:05 AM
8. Positive specific heats goes the other way around. The inhomogeneity gets larger energy for the same entropy and regrouping is favored by the release of such energy. Inhomogeneities did not grow too much. Equilibrium is stable. Fluctuations are minimal.
December 11, 2025 at 7:05 AM
7. In thermodynamics, c is related to stability. Negative c would render unstable "equilibrium" states bc if the system got divided in two, the sum of the two partition would have less energy than the total. Regrouping would be inhibited. Inhomogeneities would grow indefinitely.
December 11, 2025 at 7:04 AM
6. Many observations go in line with the vanishing of the sp heats: crystalline solid, electronic contribution, two-state models.

Quantum physics is always in the core explanation, alien to the 2nd law of thermod.

This work addresses the thermodynamic origin of the phenomenon.
December 11, 2025 at 7:03 AM
5. In 1907 Einstein provided an explantition. The second success by the emergin quantum theory. First time quantum physics was applied to real matter (ie not photons). In 1912 Debye refined the thing and got the T^3 law for the vanishing specific heats.
December 11, 2025 at 7:02 AM
4. At room temperature specific heat of solids usually range 3R (ideal gas constant) (Dulong and Petit 1819). Equipartition theorem provides explanation. At low temperature this dramatically fails to sustain. No classical explanation existed.
December 11, 2025 at 7:02 AM
3. Non-zero specific heat means energy is required to change temperature. The vanishing of the specific heats means few energy, if any, is needed to alter temperature at absolute zero. Which indirectly explains the challenging conditions around T=0.
December 11, 2025 at 7:01 AM
2. The specific heat measures the opposition to change temperature upon a given change of energy. Larger C requires more energy (u) to sustain the same change of T. Specific heat is related to the curvature of u(s) along s (entropy). More curvature--> less C --> T changes quickly.
December 11, 2025 at 7:00 AM
1. There are two general properties of matter at T=0. i) The vanishing of the change of entropy (Nernst theorem), studied in doi.org/10.1140/epjp... and ii) the vanshing of the specific heat, this work focus.
December 11, 2025 at 6:59 AM
19. Si ha llegado hasta aquí y le ha gustado esto (o incluso si no) considere, por favor, rebotar el primer comentario de este hilo.🔚

bsky.app/profile/mart...
Publico en Phys Scrp (IOP Pub) un artículo que vincula la anulación de los calores específicos en T=0 con el principio de aumento de entropía. doi.org/10.1088/1402...

Es una secuela del artículo sobre el teorema de Nernst. Completa la revisión de 3er ppo de la termodinámica.🆕🧵⤵️
December 9, 2025 at 4:45 PM
18. Este trabajo se originó tras una intervención mía en el canal de youtube @ccuanticos.bsky.social youtu.be/piz9v9Rrk98?... en el que charlé con Enriquez Fernández Borja sobre el trabajo del teorema de Nernst. (marca de tiempo 1h20min; véase tb los comentarios al vídeo)
120 Años bajo la sombra de Einstein: Entrevista al Profesor José María Martín Olalla.
YouTube video by CUENTOS CUÁNTICOS
youtu.be
December 9, 2025 at 4:44 PM
La versión preprint y su traducción al castellano están depositadas en zenodo.org/records/1779... y en el repositorio institucional hdl.handle.net/11441/179315

La versión aceptada (copyright @ioppublishing.bsky.social ) está en mi página personal personal.us.es/olalla
Thermal stability originates the vanishing of the specific heats at absolute zero
The relationship between the vanishing of the heat capacities as $T\to0^+$ and the thermal stability is examined. The heat capacities vanish as fast as or faster than $T$ as $T\to0^+$ for states at th...
zenodo.org
December 9, 2025 at 4:43 PM
16. Mi conclusión es que no es necesario un principio adicional y nuevo para explicar las propiedades generales de la materia cerca del cero absoluto. Estás propiedades son las que se deducen del segundo principio de la termodinamica.
December 9, 2025 at 4:40 PM