🚨Due to the regime cutting off the internet last 5 days messages coming out of Iran have decreased by 99% - this one made it through. The scale of civilian massacre is far beyond what has been reported. The figure of 12,000 killed is described as ‘almost a joke’ compared to the magnitude of the catastrophe that has taken place.The regime in Iran have carried out widespread and systematic deadly violence. “It is a massacre beyond human imagination”. There are subtitles so please go to the end. It is still happening. Please share widely.#IranianRevolution2026

Protesterna i Iran är så omfattande att säkerhetsstyrkorna inte räcker till för att hålla tillbaka demonstranterna.

Rare examples of trinuclear [Ni–N2–M–N2–Ni] core (M = Ca, Mg) with linear bridged dinitrogen ligands are reported in this work. The reduction of [iPr2NN]Ni(μ-Br)2Li(thf)2 (1) (iPr2NN =…

The development of stable and tunable polycyclic aromatic compounds (PACs) is crucial for the advancement of organic optoelectronics. Conventional PACs, such as acenes, often suffer from poor stability due to photooxidation and oligomerization, which are linked to their frontier molecular orbital energy levels. To address these limitations, we designed and synthesized a new class of π-expanded indoloindolizines by merging indole and indolizine moieties into a single polycyclic framework. We developed a scalable synthetic protocol to produce a wide range of π-expanded derivatives. The structural, electronic, and optical properties of these compounds were extensively characterized. We achieved precise modulation of the electronic structure by controlling the aromaticity of specific rings. Benzannulation at targeted positions allowed fine-tuning of the HOMO–LUMO gap, leading to distinct shifts in the optoelectronic properties. Single-crystal X-ray diffraction confirmed their molecular structures, while theoretical calculations provided insights into the observed experimental trends. These indoloindolizines exhibit vivid colors and fluorescence across the visible spectrum and enhanced stability against photooxidation. Reactivity studies demonstrated high regioselectivity in electrophilic substitutions, highlighting the indole-like behavior of these compounds and opening avenues for further functionalization. To showcase the practical utility of our design rules, we fabricated organic field-effect transistors (OFETs) using the newly developed indoloindolizines, which revealed remarkable performance with ambipolar charge transport properties. Overall, our work establishes indoloindolizines as a promising platform for the development of stable, tunable organic materials for optoelectronic applications. Through rational molecular design, we have provided a new pathway for molecular innovation in organic electronics.

The development of straightforward synthetic methods for photoactive polycyclic aromatic hydrocarbons (PAHs) that avoid Pd-catalyzed or radical-based processes remains a challenge. Such methods are e...

In the universe of chemical bonds, a spectrum stretches from the almost purely ionic to the perfectly covalent. Yet, amid this intricate zoo of possibilities, one elusive creature remains unseen: a mi...