Jack Wolff
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Jack Wolff
@wolffjack.bsky.social
Probably playing Mario Party
Reposted by Jack Wolff
A new paper is a great way to end the year! Check out my debut (co)first author publication in Accounts of Chemical Research. Reactivity of Anomalous Aziridines for Versatile Access to High Fsp3 Amine Chemical Space. @acspublications.bsky.social

pubs.acs.org/doi/10.1021/...
Reactivity of Anomalous Aziridines for Versatile Access to High Fsp3 Amine Chemical Space
ConspectusThe manipulation of strained rings is a powerful strategy for accessing the valuable chemical frameworks present in natural products and active pharmaceutical ingredients. Aziridines, the sm...
pubs.acs.org
December 30, 2024 at 7:43 PM
Reposted by Jack Wolff
My first publication from the Schomaker group is now out on JACS! Elucidating the Mechanism of Electrooxidative Allene Dioxygenation: Dual Role of Tetramethylpiperidine N-Oxyl (TEMPO). Congrats to Ken, Fede, and the rest of the team :) @uwmadscience.bsky.social

pubs.acs.org/doi/10.1021/...
Elucidating the Mechanism of Electrooxidative Allene Dioxygenation: Dual Role of Tetramethylpiperidine N-Oxyl (TEMPO)
The cumulated π system of a nonsymmetric allene contains three distinct unsaturated carbons that imbue it with unique reactivity toward radicals as compared to its alkene and alkyne counterparts. Desp...
pubs.acs.org
December 16, 2024 at 7:06 PM