Baihao Shao
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shaobaqian.bsky.social
Baihao Shao
@shaobaqian.bsky.social
PDRA@KavliOxford
Super cool - congrats to all!
May 4, 2025 at 8:58 PM
Reposted by Baihao Shao
The 2016 Nobel prize in chemistry was awarded 'for the design and synthesis of molecular machines'. Ironically, we do not know exactly what constitutes a molecular machine. With the ultimate goal of unifying definitions and standardising terminology, Iupac needs your help!
#ChemSky #ScienceSky
Take two polls to help Iupac define molecular machines
An Iupac committee wants your input to guide its recommendations for key terms in the field
www.chemistryworld.com
April 29, 2025 at 11:18 AM
congrats to Danii!
Click chemistry is a powerful way to stitch molecules together — but in our new @jacs.acspublications.org paper bit.ly/4cNBqMK we find that not all triazoles are equal! When it comes to #photoswitch the 1,5-regioisomer (not from "click") surprisingly outperforms the classic 1,4🧪⚗️ #molswitch #chemsky
“Clicked” Hydrazone Photoswitches
The length of the linker connecting a photoswitch to a material significantly influences the latter’s properties, with “zero-length” linkers being ideal for optimal photomodulation. The 1,2,3-triazole...
bit.ly
April 27, 2025 at 8:52 AM
Reposted by Baihao Shao
Considering the diverse backgrounds of my new followers, I'll share here a perspective I co-wrote with Steve Goldup about kinetic assymetry, and it's pivotal role in designing meaningful #out-of-equilibrium systems - including life itself! :) pubs.acs.org/doi/10.1021/...
#ChemSky 🧪⚗️
Non-equilibrium Steady States in Catalysis, Molecular Motors, and Supramolecular Materials: Why Networks and Language Matter
All chemists are familiar with the idea that, at equilibrium steady state, the relative concentrations of species present in a system are predicted by the corresponding equilibrium constants, which are related to the free energy differences between the system components. There is also no net flux between species, no matter how complicated the reaction network. Achieving and harnessing non-equilibrium steady states, by coupling a reaction network to a second spontaneous chemical process, has been the subject of work in several disciplines, including the operation of molecular motors, the assembly of supramolecular materials, and strategies in enantioselective catalysis. We juxtapose these linked fields to highlight their common features and challenges as well as some common misconceptions that may be serving to stymie progress.
pubs.acs.org
November 29, 2024 at 7:42 PM