Roushan Singh
@roushansingh.bsky.social
PhD Candidate in organometallic chemistry at Neal Mankad’s group | University of Illinois Chicago | Heterobimetallic chemistry | Main group and transition metals | IISER Bhopal alumnus
Excited to share our group's strategies to stabilize mononuclear Al radicals! Redox-active ligands + strained geometries give Al biphilic character, letting it mimic d-/f-block metals. Thanks @metallacycle.bsky.social for the guidance!
May 8, 2025 at 9:50 PM
Excited to share our group's strategies to stabilize mononuclear Al radicals! Redox-active ligands + strained geometries give Al biphilic character, letting it mimic d-/f-block metals. Thanks @metallacycle.bsky.social for the guidance!
Reposted by Roushan Singh
Hey #chemsky our latest Al-Fe research is published in @jacs.acspublications.org. Led by Roushan Singh @uic-chemistry.bsky.social and our collaboration with Dan Ess of BYU, we are starting to map the chemistry of Al(II) through this mild approach!
doi.org/10.1021/jacs...
doi.org/10.1021/jacs...
Cooperative Heterobimetallic CO2 Activation Involving a Mononuclear Aluminum(II) Intermediate
Molecular chemistry of aluminum most commonly involves AlIII ions due to their noble gas electronic configurations. In contrast, the chemistry of AlII ions is underexplored and may contain undiscovere...
doi.org
April 3, 2025 at 3:34 PM
Hey #chemsky our latest Al-Fe research is published in @jacs.acspublications.org. Led by Roushan Singh @uic-chemistry.bsky.social and our collaboration with Dan Ess of BYU, we are starting to map the chemistry of Al(II) through this mild approach!
doi.org/10.1021/jacs...
doi.org/10.1021/jacs...