Thrilled to share our recent work on Au-Sb multimetallics from Bismuto Lab
#Gold #Smallinorganicrings
#Gold #Smallinorganicrings
Congratulation to Prasenjit and Matthias for adding gold in our azadistibiridine and study the unusual stepwise dyotropic rearrangement! Now published in @chemcomm.rsc.org Thanks @tonifrontera.bsky.social for the fruitful collaboration. #Antimony #Smallrings
pubs.rsc.org/en/content/a...
pubs.rsc.org/en/content/a...
Synthesis and reactivity of a small distibacycle featuring an Au–Sb bimetallic linkage
Although unsaturated heavy dipnicta-heterocycles have recently received increasing attention, their reactivity still remains underexplored. Herein, we describe a comprehensive experimental and theoret...
pubs.rsc.org
November 15, 2025 at 3:06 PM
Thrilled to share our recent work on Au-Sb multimetallics from Bismuto Lab
#Gold #Smallinorganicrings
#Gold #Smallinorganicrings
Reposted by Prasenjit Palui
Thrilled to share the work of @clarencetankl.bsky.social and @antorna.bsky.social on elevating #sodium mediated deprotonative #borylation to #catalytic regimes with an insightful #mechanistic study in collaboration with Max Garcia Melchor @pubs.acs.org @unibe.ch
pubs.acs.org/doi/10.1021/...
pubs.acs.org/doi/10.1021/...
October 29, 2025 at 6:35 PM
Thrilled to share the work of @clarencetankl.bsky.social and @antorna.bsky.social on elevating #sodium mediated deprotonative #borylation to #catalytic regimes with an insightful #mechanistic study in collaboration with Max Garcia Melchor @pubs.acs.org @unibe.ch
pubs.acs.org/doi/10.1021/...
pubs.acs.org/doi/10.1021/...
Reposted by Prasenjit Palui
Our manuscript detailing the impact of carbene ligands on the synthesis, properties, and reactivity of 8 diazoboranes is now published in JACS (pubs.acs.org/doi/10.1021/...)! Take a look at the unusual boraketenes and diazaborles! #maingroup #boron @jacs.acspublications.org
September 26, 2025 at 1:12 AM
Our manuscript detailing the impact of carbene ligands on the synthesis, properties, and reactivity of 8 diazoboranes is now published in JACS (pubs.acs.org/doi/10.1021/...)! Take a look at the unusual boraketenes and diazaborles! #maingroup #boron @jacs.acspublications.org
Reposted by Prasenjit Palui
THIS CHALLENGING SYNTHESIS completes the (BDI)Ae-(benzene)-Ae(BDI) series (Ae = Mg, Ca, Sr, Ba) with Ba. We show trends in stability, structure, bonding and reactivity. Reacting like (BDI)Ba-Ba(BDI) this is the first Ba(I) synthon. shorturl.at/ZdToA @chemicalscience.rsc.org
September 4, 2025 at 11:00 AM
THIS CHALLENGING SYNTHESIS completes the (BDI)Ae-(benzene)-Ae(BDI) series (Ae = Mg, Ca, Sr, Ba) with Ba. We show trends in stability, structure, bonding and reactivity. Reacting like (BDI)Ba-Ba(BDI) this is the first Ba(I) synthon. shorturl.at/ZdToA @chemicalscience.rsc.org
Reposted by Prasenjit Palui
Alessandro Bismuto, University of Bonn, and colleagues have synthesized and characterized three- and four-membered heterocyclic rings containing Sb₂- or Bi₂-units, obtained from heavy dipnictenes (Sb=Sb, Bi=Bi) and different azides
www.chemistryviews.org/synthesis-an...
www.chemistryviews.org/synthesis-an...
Synthesis and Reactivity of Heavy Azadipnictiridines and Stabilized-Iminobismuthane - ChemistryViews
Synthesis and Reactivity of Heavy Azadipnictiridines
www.chemistryviews.org
August 20, 2025 at 6:14 AM
Alessandro Bismuto, University of Bonn, and colleagues have synthesized and characterized three- and four-membered heterocyclic rings containing Sb₂- or Bi₂-units, obtained from heavy dipnictenes (Sb=Sb, Bi=Bi) and different azides
www.chemistryviews.org/synthesis-an...
www.chemistryviews.org/synthesis-an...
Reposted by Prasenjit Palui
Thrilled to share a first publication of the group! We report on cadmium aluminyls that find application as Cd-nucleophiles and(!) Al(I)-Transfer reagents. Now out in @jacs.acspublications.org ! 🥳👍
Thanks a lot to @chemieverband.bsky.social for the generous funding. pubs.acs.org/doi/10.1021/...
Thanks a lot to @chemieverband.bsky.social for the generous funding. pubs.acs.org/doi/10.1021/...
Functional Al/Cd Heterometallics─From Controlled Al(I) Transfer to Nucleophilic Transfer of Cadmium Ions
Low-valent cadmium compounds have remained largely unexplored as electron reservoirs, with no precedent for their use in reduction or bond activation chemistry. Here, we address this gap by integratin...
pubs.acs.org
August 25, 2025 at 7:14 PM
Thrilled to share a first publication of the group! We report on cadmium aluminyls that find application as Cd-nucleophiles and(!) Al(I)-Transfer reagents. Now out in @jacs.acspublications.org ! 🥳👍
Thanks a lot to @chemieverband.bsky.social for the generous funding. pubs.acs.org/doi/10.1021/...
Thanks a lot to @chemieverband.bsky.social for the generous funding. pubs.acs.org/doi/10.1021/...
