Keyan Li
@keyanl.bsky.social
Chemistry graduate student at the University of Oregon interested in bio(in)organic chemistry of S and Se.
Reposted by Keyan Li
Curious about the impacts of Lewis acids on persulfide & thioselenide chemistry? Check out Keyan & Addison’s paper using isolated ZnSSR & ZnSeSR complexes to directly study reactivity. Lots of insights from 77Se NMR & XRD!
@angewandtechemie.bsky.social
onlinelibrary.wiley.com/doi/10.1002/...
@angewandtechemie.bsky.social
onlinelibrary.wiley.com/doi/10.1002/...
November 22, 2025 at 5:04 PM
Curious about the impacts of Lewis acids on persulfide & thioselenide chemistry? Check out Keyan & Addison’s paper using isolated ZnSSR & ZnSeSR complexes to directly study reactivity. Lots of insights from 77Se NMR & XRD!
@angewandtechemie.bsky.social
onlinelibrary.wiley.com/doi/10.1002/...
@angewandtechemie.bsky.social
onlinelibrary.wiley.com/doi/10.1002/...
Reposted by Keyan Li
Back in 2020, soon after I had isolated the Fe-S cluster terminal imido complex, Dan remarked “I wonder what happens if you oxidize it.” Five years later, we finally have the answer: pubs.acs.org/doi/10.1021/...
Nitrogen Subvalency in a Four-Member Redox Series of Iron–Sulfur Cluster Imido Complexes
Imido complexes of high-spin 3d metals can feature N subvalency, wherein configurations with hole character at N contribute significantly to the ground state electronic structure. Reported herein are ...
pubs.acs.org
November 3, 2025 at 1:23 PM
Back in 2020, soon after I had isolated the Fe-S cluster terminal imido complex, Dan remarked “I wonder what happens if you oxidize it.” Five years later, we finally have the answer: pubs.acs.org/doi/10.1021/...
Reposted by Keyan Li
Understanding Reactive Sulfur Species Storage from Hybrid S/N Crosstalk Species: Perthionitrite (SSNO–) and Thionitrite (SNO–) Activation by a Mononuclear Nonheme FeII Complex pubs.acs.org/doi/10.1021/... @mdpluth and co-workers @InorgChem #iron #tripodal #SSNO_ #SNO_ #S_N_hybdspecies
June 23, 2025 at 4:03 AM
Understanding Reactive Sulfur Species Storage from Hybrid S/N Crosstalk Species: Perthionitrite (SSNO–) and Thionitrite (SNO–) Activation by a Mononuclear Nonheme FeII Complex pubs.acs.org/doi/10.1021/... @mdpluth and co-workers @InorgChem #iron #tripodal #SSNO_ #SNO_ #S_N_hybdspecies