Larissa von Krbek
jjajacjack.bsky.social
Larissa von Krbek
@jjajacjack.bsky.social
#NewPI at Kekulé Institute at the University of Bonn Previously Nitschke group and Schalley group.
Out-of-equilibrium systems, metallo-cages, photoswitches, #SystemsChemistry #SupramolecularChemistry
Views are my own (she/her).
www.krbekgroup.com
Reposted by Larissa von Krbek
(3/4)💡Furthermore, #photoswitching of the helicates operates via a #MolecularRatchet mechanism, which autonomously operates under continuous white light irradiation. This results in the accumulation of a specific #out-of-equilibrium pseudo-mesocate structure

#switches
#molswitches
#SystemsChemistry
June 12, 2025 at 11:46 AM
Reposted by Larissa von Krbek
(4/4) Crucially, the Zn-helicate can #regioselectively exchange one Zn(II) for Fe(II), forming a Zn-Fe helicate. This process is significantly accelerated by #LightIrradiation via the #MolecularRatchet mechanism, reminiscent of the operation of a claw machine.

#photoswitches
#SystemsChemistry
June 12, 2025 at 11:46 AM
Reposted by Larissa von Krbek
(2/2) @medbioinorgchem.bsky.social
@boekhovenlab.bsky.social
@rjmayer.bsky.social
Fritz Kühn
Mirza Cokoja

Thank you all for making this such a wonderful visit!
June 12, 2025 at 8:12 AM