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falk-eb.bsky.social
@falk-eb.bsky.social
Anionic Dicarbene + Group 14 Element = 🪨⌬
🧑🏼‍🔬 Working with Heavy 🤘 Aromatics @ https://www.ghadwalgroup.de
Reposted
Pleased to share Falk’s latest work @ghadwalgroup.bsky.social on a non-classical germanium diradicaloid, just published in @angewandtechemie.bsky.social highlighting a new approach (using anionic dicarbenes) to main-group diradicaloids: onlinelibrary.wiley.com/doi/10.1002/... thanks to @dfg.de
Bicyclo[1.1.0]tetragermane‐2,4‐diide Diradicaloid
The bicyclo[1.1.0]tetragermane-2,4-diide diradicaloid compound [(ADC)2Ge4] featuring a stretched bridgehead Ge─Ge bond is reported as a Venetian red crystalline solid. [(ADC)2Ge4] has been characteri...
onlinelibrary.wiley.com
August 7, 2025 at 7:37 PM
Reposted
Reversible single-electron-transfer (SET) in #maingroup systems—cyclic pnictogen radicals—analogs of aryl radical anions in Birch reductions— @angewandtechemie.bsky.social Congratulations to Henric and all @ghadwalgroup.bsky.social
@basdebruin.bsky.social onlinelibrary.wiley.com/doi/10.1002/...
March 31, 2025 at 8:05 AM
Reposted
Delighted to share the first original research article of 2025 by @ghadwalgroup.bsky.social
... in @angewandtechemie.bsky.social dedicated to @remglasgow.bsky.social

thanks to @dfg.de

👉 Lithium Anionic Dicarbenes or Acetylides: What is in the Name? onlinelibrary.wiley.com/doi/10.1002/...
February 26, 2025 at 2:42 PM
Very happy to share that our research @ghadwalgroup.bsky.social on 1,4-Disilabenzenes @acsjacs.bsky.social has been highlighted in #synfacts:
www.thieme-connect.com/products/ejo...
1,4-Disilabenzenes: Low-Valent Silicon Aromaticity
Thieme E-Books & E-Journals
www.thieme-connect.com
January 30, 2025 at 11:55 AM
Reposted
Excited to share this fantastic collaboration with
Ghadwal_Group just published in JACS @acspublications.bsky.social on Carbon Dioxide Capture and (De)oxygenation at Group 14 Diradicaloids
pubs.acs.org/doi/10.1021/...
Structural Snapshots of Reversible Carbon Dioxide Capture and (De)oxygenation at Group 14 Diradicaloids
Although diradicals should exhibit a rather small reaction barrier as compared to closed-shell species for activating kinetically inert molecules, the activation and functionalization of carbon dioxid...
pubs.acs.org
December 9, 2024 at 8:43 AM