PhD Project - Metals against AMR - Understanding how bismuth inhibits metallo-β-lactamase enzymes at Nottingham Trent University, listed on FindAPhD.com

PhD Project - [FSE Bicentenary PhD] Controlling magnetic relaxation times in rare earth single-molecule magnets and qubits at The University of Manchester, listed on FindAPhD.com

PhD Project - Sustainable Catalysis with Sb and Bi Pincer Complexes at The University of Manchester, listed on FindAPhD.com

PhD Project - [FSE Bicentenary PhD] New Electrosynthetic Strategies to Nitrile Covalent Warheads, and Their Application to the Development of Electrochemically-Activated Prodrugs for Targeted Drug-De...

Rapid washout: Cocktail-treated RBCs can be washed and prepared for transfusion in just 25 minutes – compared to over 75 minutes for glycerol.Higher recovery rates: The new method results in an averag...

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p-Block complexes containing unsupported metal–metal bonds can activate small molecules via mechanisms that complement and contrast with those of d-block metal complexes. Within this compound class, A...

Reductive amination is a challenging reaction in catalysis that often gives poor yield and selectivity. We present an ironcatalyzed approach of synthesizing amines through reduction of nitriles throu...

And holds up the pace of scientific progress

PhD Project - (EPSRC DTP) Combining experiment and theory to understand dynamic ordering of molecules in liquid solutions that influences physical properties of drug-like molecules and reactivity at T...

MSCA Postdoctoral Fellowships enhance the creative and innovative potential of researchers holding a PhD and who wish to acquire new skills through advanced training, international, interdisciplinary ...

PhD Project - PhD in Chemistry: Synthesis of Transition Metal Precursors for Semiconductor Materials at Cardiff University, listed on FindAPhD.com

FindAPhD. Search Funded PhD Projects, Programmes & Scholarships at Cardiff University.

Thrilled to see our AZD5991 route design article published in #OPRD. Thanks to everyone who was involved! https://lnkd.in/eCp-ipfK After AstraZeneca…

Lanthanide (Ln) magnetic resonance imaging and chiral shift reagents generally exploit 1H NMR shifts, as paramagnetic broadening tends to preclude the use of heavier, less sensitive nuclei. Here, we report the solution and solid-state 31P NMR shifts of an isostructural series of distorted trigonal bipyramidal Ln(III) tris-silylphosphide complexes, [Ln{P(SiMe3)2}3(THF)2] (1-Ln; Ln = La, Ce, Pr, Nd, Sm); 1-Ln was also characterized by elemental analysis; single-crystal and powder X-ray diffraction; multinuclear NMR, EPR, ATR-IR, and UV–vis-NIR spectroscopy; and SQUID magnetometry. Breaking assumptions, we observed paramagnetically broadened 31P NMR spectra for the Ln-bound P atoms for the 1-Ln family; in solution, 1-Nd showed the most downfield chemical shift (δ{31P} = 2570.14 ppm) and 1-Sm the most upfield value (δ{31P} = −259.21 ppm). We determined the span of the chemical shift anisotropies (CSAs) for solid 1-Ln using magic angle spinning NMR spectroscopy; the CSA was largest for 1-Pr (Ω{31P} ≈ 2000 ppm), consistent with a combination of paramagnetism and the relatively large differences in pyramidalization of the three P atoms in the solid-state. Density functional theory calculations for 1-La were in excellent agreement with the experimentally determined 31P NMR parameters. We find good agreement of experimental 1H NMR chemical shifts with ab initio-calculated values for paramagnetic 1-Ln, while the shifts of heavier 13C, 29Si, and 31P nuclei are not well-reproduced due to the current limitations of paramagnetic NMR calculations for nuclei with large contact shifts.

PhD Project - PhD in Chemistry: Safe Removal and Recovery of the Heavier Group 15 Compounds (Bi, Sb, As): EPSRC IDLA PhD at Cardiff University, listed on FindAPhD.com

gem-Dichlorocyclopropanes are important structural moieties in a range of industrial sectors and have been the focus of considerable interest within the synthetic community over the years. Synthetic m...