Colton Johnson
@coltonejohnson.bsky.social
Big fan of total synthesis and catalysis | PhD student in the Lautens group @UofT | Former undergraduate @UBC
Reposted by Colton Johnson
Also in @science.org this week, Max Hansmann’s group return with yet another convenient C-atom transfer agent. This time, a diazo/sulfur ylide hybrid favors spiro-type sp3 products from olefins
chemsky 🧪
www.science.org/doi/10.1126/...
chemsky 🧪
www.science.org/doi/10.1126/...
Spiro-C(sp3)-atom transfer: Creating rigid three-dimensional structures with Ph2SCN2
The introduction of a single C-atom into organic substrates typically results in the formation of flat molecules containing unsaturated C(sp)-centers. Adding a single C(sp3)-atom surrounded by four σ-...
www.science.org
February 20, 2025 at 7:17 PM
Also in @science.org this week, Max Hansmann’s group return with yet another convenient C-atom transfer agent. This time, a diazo/sulfur ylide hybrid favors spiro-type sp3 products from olefins
chemsky 🧪
www.science.org/doi/10.1126/...
chemsky 🧪
www.science.org/doi/10.1126/...
Hi, I’d love to be included on this list!
December 9, 2024 at 5:00 AM
Hi, I’d love to be included on this list!
iirc it’s from a Swern byproduct, I think the authors tried other amines and didn’t see this byproduct, so perhaps one of the latter steps also affects it.
December 2, 2024 at 10:33 PM
iirc it’s from a Swern byproduct, I think the authors tried other amines and didn’t see this byproduct, so perhaps one of the latter steps also affects it.