Scientificpublications Scientific publications Explore our documents Davydiuk, N., et al. The rising danger of AI-generated images in nanomaterials science and what we can do about it. Nature Nanotech...

Chiral plasmonic nanomaterials display strong interactions with circularly polarized light, offering significant potential in chirality sensing, enantioselective catalysis, and biomedical applications. While recent advances in seeded-growth synthesis have yielded complex chiral gold nanostructures through chemically induced or micelle-directed growth mechanisms, detailed intercorrelated mechanisms remain elusive. In this context, we have systematically investigated the versatility of the chiral inducer 2-amino-N-decyl-3-mercaptopropanamide (LipoCYS), which incorporates both an amino acid moiety and an aliphatic chain designed to bridge both established mechanisms. By employing cubic and octahedral achiral gold seeds and varying the surfactant halides, along with the concentration of LipoCYS, we generated a wide range of chiral morphologies, from twisted helicoids to intricate wrinkled spheres and intermediate structures. Advanced electron microscopy, including electron tomography, enabled comprehensive three-dimensional characterization and revealed distinct chiral morphological transitions and their correlations with chiroptical properties. Excellent agreement was found with the simulation results, thereby validating the representativeness of the microscopic analysis. Our findings expand the synthetic toolbox available for the precise control of nanoparticle chirality, providing deeper insights into the mechanisms of chiral growth and enhancing their potential for tailored applications.

The SERS spectra of reporter molecules adsorbed on chiral gold nanorods depends on the handedness of circularly polarized light (CPL-SERS). The bisignate plasmonic CD spectra of chiral nanorods provi...

New interdisciplinary global research project to develop infrastructure for nanostructures to advance the frontiers of biosensing and metamaterials.

Temporary full time contract in the framework of the research project

The increasing interest in plasmonic nanoparticles with intrinsic chirality, i.e., reduced symmetry and strong optical activity, calls for characterization beyond qualitative imaging. In this context,...