Stas Melnikov
@melnikovs.bsky.social
PhD student at Utrecht University
Feel very happy that my 2nd PhD paper is out!
Role of Quantum Tunneling in Metal-Ligand Proton Tautomerism - now on @chemrxiv.org LINK: go.shr.lc/3JfczH3
Role of Quantum Tunneling in Metal-Ligand Proton Tautomerism - now on @chemrxiv.org LINK: go.shr.lc/3JfczH3
August 15, 2025 at 12:10 PM
Feel very happy that my 2nd PhD paper is out!
Role of Quantum Tunneling in Metal-Ligand Proton Tautomerism - now on @chemrxiv.org LINK: go.shr.lc/3JfczH3
Role of Quantum Tunneling in Metal-Ligand Proton Tautomerism - now on @chemrxiv.org LINK: go.shr.lc/3JfczH3
Proud of our latest work! We report an unusual example of Nucleophilic Aromatic Substitution on benzene, where hydride acts as the leaving group and KHMDS is used as a base. A rare case of SNArH with a non-nucleophilic base! @chemicalscience.rsc.org
pubs.rsc.org/en/content/a...
#MyFirstChemSci
pubs.rsc.org/en/content/a...
#MyFirstChemSci
Ruthenium-Mediated Nucleophilic Aromatic Substitution of Hydrogen in Benzene
The direct functionalization of unactivated hydrocarbons remains a significant challenge in modern chemistry. In this study, we demonstrate that a simple ruthenium complex featuring a chelating tBuPN ...
pubs.rsc.org
June 16, 2025 at 12:41 PM
Proud of our latest work! We report an unusual example of Nucleophilic Aromatic Substitution on benzene, where hydride acts as the leaving group and KHMDS is used as a base. A rare case of SNArH with a non-nucleophilic base! @chemicalscience.rsc.org
pubs.rsc.org/en/content/a...
#MyFirstChemSci
pubs.rsc.org/en/content/a...
#MyFirstChemSci
Reposted by Stas Melnikov
Dicky Wong (@thwongax.bsky.social ) has explored the chemistry of iridium complexes with N-heterocyclic vinylidene ligands. Just published in JACS (@jacs.acspublications.org ): pubs.acs.org/doi/10.1021/...
#chemsky #EPFL
#chemsky #EPFL
May 30, 2025 at 12:25 PM
Dicky Wong (@thwongax.bsky.social ) has explored the chemistry of iridium complexes with N-heterocyclic vinylidene ligands. Just published in JACS (@jacs.acspublications.org ): pubs.acs.org/doi/10.1021/...
#chemsky #EPFL
#chemsky #EPFL
Reposted by Stas Melnikov
PREFORMED REDOX-ACTIVE INVERSE CROWNS: Finally out in @naturechemistry.bsky.social Highly selective reduction of N2O, epoxide, sulfur or O2. The ring can also be extended to a larger metalla-crown for stabilization of larger anions like N2O2(2-). Open access: shorturl.at/LZE6Y
February 17, 2025 at 4:21 PM
PREFORMED REDOX-ACTIVE INVERSE CROWNS: Finally out in @naturechemistry.bsky.social Highly selective reduction of N2O, epoxide, sulfur or O2. The ring can also be extended to a larger metalla-crown for stabilization of larger anions like N2O2(2-). Open access: shorturl.at/LZE6Y