Do you have strong quantitative skills and would you like to apply these to study possible tensions between crime prevention, data privacy and non-discrimination? Apply for a PhD position at Vrije Uni...

In various regulatory settings, firms receive feedback (i.e., firm-specific private advice) from authorities on how to improve compliance. Although the literature sheds light on the authorities' deci....

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Get a day-by-day look at how Trump’s trade war has unfolded and where it stands now.

President Trump and his advisers say his policies may cause short-term pain but will produce big gains over time. Many economists are skeptical of those arguments.

Electrochemical methodologies offer a transformative approach to sustainable chemical synthesis by enabling precise, energy-efficient transformations. Here, we report the selective electrochemical N-formylation of methylamine using methanol as both reagent and solvent, facilitated by a simple glassy carbon electrode. Under optimized conditions, we achieve a faradaic efficiency (FE) of 34% for methylformamide synthesis in a neutral NaClO4 electrolyte. Mechanistic insights from in situ Fourier-transform infrared spectroscopy (FTIR) and complementary synthetic experiments reveal two distinct reaction pathways: the direct oxidation of a hemiaminal intermediate and a novel route involving the formation of methylisocyanide, which subsequently hydrates to yield methylformamide. The presence of methylisocyanide was confirmed through mass spectrometry analysis following a successful Ugi multicomponent reaction, demonstrating the ability to safely utilize reactive intermediates within an electrochemical framework. This work underscores the potential of electrosynthesis to unlock metal-free, sustainable pathways to produce value-added nitrogen-containing compounds, paving the way for greener approaches in chemical manufacturing and catalysis.

President Trump is remaking the tax code to favor the well-off even more and cloaking these changes in a veneer of nationalism.